ENTROPY AND THERMOKINETICS OF TOLUENE ADSORPTION ON Cu2+ZSM-5 ZEOLITE

Authors

  • Esonkulova Nazirahon Namangan Institute of Engineering and Technology
  • Bakhronov Khayot Tashkent University of Information Technologies named after Muhammad al-Khwarazmi
  • Absalyamova Ilmira Tashkent University of Information Technologies named after Muhammad al-Khwarazmi
  • Ahkmadov Majidjon Tashkent University of Information Technologies named after Muhammad al-Khwarazmi

Abstract

This paper presents the results of the main (H, F and S) thermodynamic characteristics and the time of establishment of adsorption equilibrium depending on the amount of adsorption of toluene in Cu2+ZSM-5 zeolite. The isotherms and differential heat of adsorption were measured using a system consisting of a universal high-vacuum adsorption unit and a differential modified microcalorimeter of the Tiana-Calve DAK-1-1A type connected to it, which directly gives quantitative and qualitative characteristics of the nature and forces of adsorption interaction. A correlation between the adsorption-energy characteristics was found and the molecular mechanism of toluene adsorption in Cu2+ZSM-5 zeolite was revealed in the entire filling area. It has been determined that the average molar entropy of toluene adsorption in CuZSM-5 zeolite indicates that the mobility of toluene molecules in the zeolite is lower than the liquid phase and is close to the mobility of the solid phase, which indicates a strong inhibition of the mobility of toluene molecules on cations.

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Published

2023-04-26

How to Cite

Esonkulova Nazirahon, Bakhronov Khayot, Absalyamova Ilmira, & Ahkmadov Majidjon. (2023). ENTROPY AND THERMOKINETICS OF TOLUENE ADSORPTION ON Cu2+ZSM-5 ZEOLITE. E Conference Zone, 40–44. Retrieved from http://econferencezone.org/index.php/ecz/article/view/2137

Issue

2023: ICDE-Turkey-April

Section

Articles

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Creative Commons License

This work is licensed under a Creative Commons Attribution 4.0 International License.

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